Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems

LI Si-wei; Sarfraz Rubab; YANG Wen-hao; MAO Yan-ling; ZHOU Bi-qing; XING Shi-he

doi:10.19303/j.issn.1008-0384.2019.10.015

Volume 34 Issue 10

Oct. 2019

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Article Navigation > Fujian Journal of Agricultural Sciences > 2019 > 34(10): 1211-1220

LI S W, Sarfraz Rubab, YANG W H, et al. Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems [J]. Fujian Journal of Agricultural Sciences，2019，34（10）：1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015

Citation:

LI S W, Sarfraz Rubab, YANG W H, et al. Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems [J]. Fujian Journal of Agricultural Sciences，2019，34（10）：1211−1220. doi: 10.19303/j.issn.1008-0384.2019.10.015

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Effect of Pyrolysis Temperature and Time on Structure of Biochar Made from Discarded Mushroom Stems

doi: 10.19303/j.issn.1008-0384.2019.10.015

LI Si-wei^1
,,
Sarfraz Rubab¹,
YANG Wen-hao^{1, 2
,
,},
MAO Yan-ling^{1, 2},
ZHOU Bi-qing^{1, 2},
XING Shi-he^{1, 2}

1.
College of Resources and Environmental Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian　350002, China
2.
Fujian Provincial Key Laboratory of Soil Environmental Health and Regulations, Fuzhou, Fujian　350002, China

Received Date: 2019-06-12
Rev Recd Date: 2019-08-21
Publish Date: 2019-10-01

Abstract

Abstract

Objective The surface property, which closely relates to the functionality, of biochar made from discarded mushroom stems under varied pyrolysis temperature and time was studied. Method Waste of edible mushrooms including Hypsizygus marmoreus , Pleurotus geesteranus , and Tremella fuciformis was processed under oxygen-limited pyrolysis at 400℃, 500℃, 600℃ or 700℃ for 1.5 h, 2.0 h, 2.5 h or 3.0 h. The structure property of the resulting biochar samples was analyzed using Fourier transform infrared spectroscopy (FTIR). Result The increasing pyrolysis temperature and time reduced the relative contents of C=O and C-N in the proteins, C-O-C in the celluloses, and C-H functional groups in the benzene rings of the raw material, while raised the relative contents of C-C functional groups in the benzene rings reaching a maximum when processed at 700℃ for 3.0 h. Among the 3 biochar samples obtained under same pyrolysis conditions, the maximum absorption by the oxygen functional groups of H. marmoreus biochar was the highest, and that of T. fuciformis the lowest; whereas, that by the C-C functional groups in the benzene rings of P. geesteranus biochar was the highest, and T. fuciformis biochar the lowest. Conclusion Increased pyrolysis temperature and time decomposed the organic substances such as proteins, polysaccharides, and fatty acids in the raw mushroom material, diminished the alkyls, and formed aromatics in the biochar. Processed under 700℃/3.0 h pyrolysis, the biochar attained a stable structure. As indicated by the analytical results, the H. marmoreus biochar was expected to be most effective among the 3 materials in removing heavy metals or organic pollutants, and the P. geesteranus biochar in carbon-sequestrating in soil.
- FTIR,
- discarded mushroom stem,
- biochar,
- pyrolysis temperature,
- pyrolysis time

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References(36)

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