臭氧氧化水中多菌灵的动力学研究
Ozonation knetics of aqueous carbendazim
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摘要: 在半序批反应器中,研究了O3氧化水中多菌灵的动力学,确定了相对于O3和水中多菌灵的臭氧化反应的反应级数。结果表明,O3氧化多菌灵为准2级反应,水中多菌灵的臭氧化反应速率方程为:k=1.11×exp(-48864/RT)(L·mol-1·s-1),表观反应活化能约为48.86 kJ·mol-1。Abstract: In a semi-batch reactor,the ozonation kinetics of aqueous carbendazim was explored.The reaction order relative to both dissolved ozone and carbendazim belonged to a first-order type.Thus,the ozonation of aqueous carbendazim followed a quasi-second order reaction.Furthermore,the reaction rate constant was given as k=1.11譭xp (-48864/RT) (L·mol-1·s-1),the apparent activation energy was about 48.86 kJ·mol-1.